description: |-
  ---------------------------------------------------------------------------
    n-Dodecane high temperature skeletal model based on FFCM-2
    Thermochemistry refitted to 9999 K even though the listed maximum temperature value is 6000 K.
  ---------------------------------------------------------------------------

units: {length: cm, quantity: mol, activation-energy: cal/mol}

phases:
- name: gas
  thermo: ideal-gas
  elements: [H, O, Ar, N, C]
  species: [H, H2, O, O2, OH, H2O, HO2, H2O2, AR, N2, CH2, CH2(S), CH3,
    CH4, CO, CO2, HCO, CH2O, CH3O, C2H, C2H2, C2H3, C2H4, C2H5, C2H6, HCCO,
    CH2CO, CH2CHO, H2CC, IC3H7, C3H6, C3H5, AC3H4, PC3H4, C2H3CHO, C4H2,
    IC4H3, C4H4, IC4H5, C4H6, C4H7, C4H81, NC12H26]
  kinetics: gas
  reactions: all
  transport: mixture-averaged
  state:
    T: 300.0
    P: 1.01325e+05

species:
- name: H
  composition: {H: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.5, 0.0, 0.0, 0.0, 0.0, 2.547366e+04, -0.44668285]
    - [2.5, 0.0, 0.0, 0.0, 0.0, 2.547366e+04, -0.44668285]
  transport:
    model: gas
    geometry: atom
    diameter: 2.05
    well-depth: 145.0
- name: H2
  composition: {H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.34433112, 7.98052075e-03, -1.9478151e-05, 2.01572094e-08, -7.37611761e-12,
      -917.935173, 0.683010238]
    - [2.9520759, 7.91666196e-04, -1.274133e-07, 1.19875367e-11, -5.23682185e-16,
      -820.3119, -1.13048079]
  transport:
    model: gas
    geometry: linear
    diameter: 2.92
    well-depth: 38.0
    polarizability: 0.79
    rotational-relaxation: 280.0
- name: O
  composition: {O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.1682671, -3.27931884e-03, 6.64306396e-06, -6.12806624e-09, 2.11265971e-12,
      2.91222592e+04, 2.05193346]
    - [2.56538217, -7.02914756e-05, 2.27315524e-08, -1.18104352e-12, -3.55075505e-17,
      2.92182256e+04, 4.80353266]
  transport:
    model: gas
    geometry: atom
    diameter: 2.75
    well-depth: 80.0
- name: O2
  composition: {O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.78245636, -2.99673416e-03, 9.84730201e-06, -9.68129509e-09, 3.24372837e-12,
      -1063.94356, 3.65767573]
    - [3.70948099, 5.61169356e-04, -8.20795189e-08, 7.22607708e-12, -3.39407909e-16,
      -1233.44284, 3.15006889]
  transport:
    model: gas
    geometry: linear
    diameter: 3.458
    well-depth: 107.4
    polarizability: 1.6
    rotational-relaxation: 3.8
- name: OH
  composition: {H: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.99198424, -2.40106655e-03, 4.61664033e-06, -3.87916306e-09, 1.36319502e-12,
      3368.89836, -0.103998477]
    - [2.90694277, 9.7155978e-04, -2.08015333e-07, 2.20250266e-11, -9.22255342e-16,
      3673.37166, 5.47153728]
  transport:
    model: gas
    geometry: linear
    diameter: 2.75
    well-depth: 80.0
- name: H2O
  composition: {H: 2, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.1986352, -2.0364017e-03, 6.5203416e-06, -5.4879269e-09, 1.771968e-12,
      -3.0293726e+04, -0.84900901]
    - [2.7421166, 2.85096424e-03, -7.03159964e-07, 8.00750327e-11, -3.37978141e-15,
      -2.99099876e+04, 6.52448592]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 2.605
    well-depth: 572.4
    dipole: 1.844
    rotational-relaxation: 4.0
- name: HO2
  composition: {H: 1, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.30179807, -4.74912097e-03, 2.11582905e-05, -2.42763914e-08, 9.29225225e-12,
      264.018485, 3.7166622]
    - [4.13201992, 1.96570213e-03, -4.03973098e-07, 3.41040628e-11, -1.0246077e-15,
      44.8377788, 3.17557753]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.458
    well-depth: 107.4
    rotational-relaxation: 1.0
- name: H2O2
  composition: {H: 2, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.31515149, -8.47390622e-04, 1.76404323e-05, -2.26762944e-08, 9.08950158e-12,
      -1.77067437e+04, 3.27373319]
    - [4.86986787, 3.47503715e-03, -9.30475678e-07, 1.11851816e-10, -4.88084945e-15,
      -1.81105314e+04, -0.917538711]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.458
    well-depth: 107.4
    rotational-relaxation: 3.8
- name: AR
  composition: {Ar: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.5, 0.0, 0.0, 0.0, 0.0, -745.375, 4.37967491]
    - [2.5, 0.0, 0.0, 0.0, 0.0, -745.375, 4.37967491]
  transport:
    model: gas
    geometry: atom
    diameter: 3.33
    well-depth: 136.5
- name: N2
  composition: {N: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.53100528, -1.23660988e-04, -5.02999433e-07, 2.43530612e-09, -1.40881235e-12,
      -1046.97628, 2.96747038]
    - [3.07095739, 1.16064408e-03, -3.42038541e-07, 4.32099807e-11, -1.93428028e-15,
      -966.086135, 5.22622896]
  transport:
    model: gas
    geometry: linear
    diameter: 3.621
    well-depth: 97.53
    polarizability: 1.76
    rotational-relaxation: 4.0
- name: CH2
  composition: {C: 1, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.71757846, 1.2739126e-03, 2.17347251e-06, -3.488585e-09, 1.65208866e-12,
      4.58723866e+04, 1.75297945]
    - [3.35782351, 2.61338564e-03, -7.25306996e-07, 8.62333957e-11, -3.66831544e-15,
      4.59661117e+04, 3.57032846]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.8
    well-depth: 144.0
    rotational-relaxation: 1.0
- name: CH2(S)
  composition: {C: 1, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.19331325, -2.33105184e-03, 8.15676451e-06, -6.62985981e-09, 1.93233199e-12,
      5.03662246e+04, -0.74673431]
    - [3.30030891, 2.56419355e-03, -6.03129156e-07, 6.2550128e-11, -2.42533492e-15,
      5.04454197e+04, 3.1595086]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.8
    well-depth: 144.0
    rotational-relaxation: 1.0
- name: CH3
  composition: {C: 1, H: 3}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.6571797, 2.1265979e-03, 5.4583883e-06, -6.6181003e-09, 2.4657074e-12,
      1.6422716e+04, 1.6735354]
    - [3.43620288, 4.87930841e-03, -1.38564426e-06, 1.67083517e-10, -7.17746574e-15,
      1.63469629e+04, 2.22578848]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.8
    well-depth: 144.0
    rotational-relaxation: 1.0
- name: CH4
  composition: {C: 1, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.14911468, -0.0136622009, 4.91453921e-05, -4.84246767e-08, 1.66603441e-11,
      -1.02465983e+04, -4.63848842]
    - [2.4932921, 8.37355613e-03, -2.28690534e-06, 3.02585971e-10, -1.45556206e-14,
      -1.03113908e+04, 5.31397972]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.746
    well-depth: 141.4
    polarizability: 2.6
    rotational-relaxation: 13.0
- name: CO
  composition: {C: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.5795335, -6.1035369e-04, 1.0168143e-06, 9.0700586e-10, -9.0442449e-13,
      -1.4344086e+04, 3.5084093]
    - [3.17258069, 1.10359587e-03, -3.27175162e-07, 4.14329256e-11, -1.85879542e-15,
      -1.43102313e+04, 5.34046783]
  transport:
    model: gas
    geometry: linear
    diameter: 3.65
    well-depth: 98.1
    polarizability: 1.95
    rotational-relaxation: 1.8
- name: CO2
  composition: {C: 1, O: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.356813, 8.9841299e-03, -7.1220632e-06, 2.4573008e-09, -1.4288548e-13,
      -4.8371971e+04, 9.9009035]
    - [4.85764063, 2.30552004e-03, -7.23423868e-07, 9.81929661e-11, -4.63468387e-15,
      -4.91042467e+04, -3.14310478]
  transport:
    model: gas
    geometry: linear
    diameter: 3.763
    well-depth: 244.0
    polarizability: 2.65
    rotational-relaxation: 2.1
- name: HCO
  composition: {C: 1, H: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.2375461, -3.32075257e-03, 1.40030264e-05, -1.34239995e-08, 4.37416208e-12,
      3872.41185, 3.30834869]
    - [4.20019156, 1.94963323e-03, -2.91634358e-07, 1.1698012e-11, 9.40138612e-17,
      3555.34962, 2.05828041]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.59
    well-depth: 498.0
    rotational-relaxation: 2.0
- name: CH2O
  composition: {C: 1, H: 2, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.79372312, -9.90833322e-03, 3.7321999e-05, -3.79285237e-08, 1.31772641e-11,
      -1.43791953e+04, 0.602798058]
    - [3.75742724, 5.01194717e-03, -1.4897266e-06, 1.84553258e-10, -8.07176413e-15,
      -1.47569999e+04, 2.83883384]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.59
    well-depth: 498.0
    rotational-relaxation: 2.0
- name: CH3O
  composition: {C: 1, H: 3, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.71180502, -2.80463306e-03, 3.76550971e-05, -4.73072089e-08, 1.8658842e-11,
      1295.6976, 6.57240864]
    - [5.46210211, 6.02605366e-03, -1.78520603e-06, 2.20582334e-10, -9.62991757e-15,
      128.571459, -5.80422954]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.69
    well-depth: 417.0
    dipole: 1.7
    rotational-relaxation: 2.0
- name: C2H
  composition: {C: 2, H: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.89867676, 0.0132988489, -2.80733327e-05, 2.89484755e-08, -1.07502351e-11,
      6.7061605e+04, 6.18547632]
    - [3.96790119, 3.21375188e-03, -9.74640977e-07, 1.20663788e-10, -5.24252969e-15,
      6.70599862e+04, 2.25830915]
  transport:
    model: gas
    geometry: linear
    diameter: 4.1
    well-depth: 209.0
    rotational-relaxation: 2.5
- name: C2H2
  composition: {C: 2, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [0.808679682, 0.0233615762, -3.55172234e-05, 2.80152958e-08, -8.50075165e-12,
      2.63076808e+04, 13.9396761]
    - [4.99276227, 4.22565137e-03, -1.196756e-06, 1.52916753e-10, -6.9977656e-15,
      2.55172487e+04, -5.82323021]
  transport:
    model: gas
    geometry: linear
    diameter: 4.1
    well-depth: 209.0
    rotational-relaxation: 2.5
- name: C2H3
  composition: {C: 2, H: 3}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.36377642, 2.65765722e-04, 2.79620704e-05, -3.72986942e-08, 1.51590176e-11,
      3.44749589e+04, 7.91510092]
    - [4.78819398, 6.26011693e-03, -1.80700356e-06, 2.20153072e-10, -9.52455126e-15,
      3.36303869e+04, -1.74838811]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.1
    well-depth: 209.0
    rotational-relaxation: 1.0
- name: C2H4
  composition: {C: 2, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.95920063, -7.57051373e-03, 5.70989993e-05, -6.91588352e-08, 2.6988419e-11,
      5089.77598, 4.09730213]
    - [4.92146111, 8.61691035e-03, -2.51631782e-06, 3.08627201e-10, -1.34108914e-14,
      3939.07619, -5.3348867]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.971
    well-depth: 280.8
    rotational-relaxation: 1.5
- name: C2H5
  composition: {C: 2, H: 5}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.24185905, -3.56905235e-03, 4.82667202e-05, -5.85401009e-08, 2.25804514e-11,
      1.29690344e+04, 4.44703782]
    - [5.4191778, 0.0101890573, -2.97770871e-06, 3.65192583e-10, -1.58416604e-14,
      1.17870723e+04, -5.80751182]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.302
    well-depth: 252.3
    rotational-relaxation: 1.5
- name: C2H6
  composition: {C: 2, H: 6}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.29142572, -5.50154901e-03, 5.99438458e-05, -7.08466469e-08, 2.68685836e-11,
      -1.15222056e+04, 2.66678994]
    - [5.423111, 0.0125888847, -3.69000079e-06, 4.53359972e-10, -1.96956187e-14,
      -1.29351713e+04, -8.46872452]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.302
    well-depth: 252.3
    rotational-relaxation: 1.5
- name: HCCO
  composition: {C: 2, H: 1, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [1.87607969, 0.0221205418, -3.58869325e-05, 3.05402541e-08, -1.01281069e-11,
      2.0163384e+04, 13.696829]
    - [6.22993849, 3.08335599e-03, -8.9753398e-07, 1.1095074e-10, -4.87503501e-15,
      1.92476647e+04, -7.22378235]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 2.5
    well-depth: 150.0
    rotational-relaxation: 1.0
- name: CH2CO
  composition: {C: 2, H: 2, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.13241136, 0.0181319455, -1.74093315e-05, 9.3533604e-09, -2.01724844e-12,
      -7148.0852, 13.3807969]
    - [6.32760371, 5.20890726e-03, -1.52444595e-06, 1.8721453e-10, -8.14217947e-15,
      -8287.00504, -8.06486433]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.97
    well-depth: 436.0
    rotational-relaxation: 2.0
- name: CH2CHO
  composition: {C: 2, H: 3, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.66873956, 9.62329538e-03, 1.60617438e-05, -2.8768182e-08, 1.25030066e-11,
      564.138429, 12.5694476]
    - [6.71132496, 7.25013349e-03, -2.12217995e-06, 2.60663233e-10, -1.13383415e-14,
      -984.891409, -10.4383147]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 3.97
    well-depth: 436.0
    rotational-relaxation: 2.0
- name: H2CC
  composition: {C: 2, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.28154941, 6.9764265e-03, -2.38527914e-06, -1.21077631e-09, 9.82041734e-13,
      4.83191706e+04, 5.92035686]
    - [4.66002113, 3.99028613e-03, -1.13810218e-06, 1.37686074e-10, -5.92895083e-15,
      4.7878522e+04, -1.44173132]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.1
    well-depth: 209.0
    rotational-relaxation: 2.5
- name: IC3H7
  composition: {C: 3, H: 7}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.47421257, -8.42536682e-03, 8.04607759e-05, -9.49287824e-08, 3.59830971e-11,
      9049.39013, 3.40542323]
    - [6.99203959, 0.0155979788, -4.56138139e-06, 5.59565429e-10, -2.42661168e-14,
      7189.99507, -11.4192299]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.982
    well-depth: 266.8
    rotational-relaxation: 1.0
- name: C3H6
  composition: {C: 3, H: 6}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.83464468, 3.29078952e-03, 5.05228001e-05, -6.66251176e-08, 2.63707473e-11,
      788.717123, 7.53408013]
    - [7.51166854, 0.0133372787, -3.91571311e-06, 4.81566648e-10, -2.09368471e-14,
      -1263.71451, -16.4641072]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.678
    well-depth: 298.9
    rotational-relaxation: 1.0
- name: C3H5
  composition: {C: 3, H: 5}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [1.65533607, 0.016368875, 2.10544223e-05, -4.24018394e-08, 1.92638759e-11,
      1.88544047e+04, 16.1040987]
    - [7.87691349, 0.0108379303, -3.14117806e-06, 3.836286e-10, -1.66243751e-14,
      1.66232329e+04, -18.6859882]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.76
    well-depth: 252.0
    rotational-relaxation: 1.0
- name: AC3H4
  composition: {C: 3, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.6130445, 0.012122575, 1.853988e-05, -3.4525149e-08, 1.5335079e-11,
      2.1541567e+04, 10.226139]
    - [7.31530035, 9.1288556e-03, -2.67275435e-06, 3.2830803e-10, -1.4280378e-14,
      1.97635565e+04, -16.4363366]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.76
    well-depth: 252.0
    rotational-relaxation: 1.0
- name: PC3H4
  composition: {C: 3, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.6803869, 0.015799651, 2.5070596e-06, -1.3657623e-08, 6.6154285e-12,
      2.0802374e+04, 9.8769351]
    - [7.03264731, 9.31385587e-03, -2.72088958e-06, 3.33797357e-10, -1.45070699e-14,
      1.92637935e+04, -14.0939674]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.76
    well-depth: 252.0
    rotational-relaxation: 1.0
- name: C2H3CHO
  composition: {C: 3, H: 4, O: 1}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.69868861, 4.99965957e-03, 4.38587397e-05, -6.128839e-08, 2.48508985e-11,
      -9718.6286, 7.29812046]
    - [9.41149022, 0.0104285933, -3.08404643e-06, 3.80138308e-10, -1.65789807e-14,
      -1.19419383e+04, -21.5536071]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.958
    well-depth: 428.8
    rotational-relaxation: 1.0
- name: C4H2
  composition: {C: 4, H: 2}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [-0.502389168, 0.0525164044, -9.29945578e-05, 8.17206506e-08, -2.73537313e-11,
      5.38574848e+04, 20.6780532]
    - [9.23905508, 5.57465552e-03, -1.61620027e-06, 1.97422869e-10, -8.55646425e-15,
      5.20392344e+04, -25.022774]
  transport:
    model: gas
    geometry: linear
    diameter: 4.72
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: IC4H3
  composition: {C: 4, H: 3}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [3.3796417, 0.027049884, -2.90761572e-05, 1.83027765e-08, -4.81164203e-12,
      5.83688723e+04, 10.5464883]
    - [9.29492754, 7.46145419e-03, -2.16499205e-06, 2.64584192e-10, -1.14707965e-14,
      5.68269268e+04, -19.3693234]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: C4H4
  composition: {C: 4, H: 4}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [1.37368786, 0.0288801256, -1.46863874e-05, -3.91045446e-09, 4.78133572e-12,
      3.30633344e+04, 17.5941274]
    - [9.02819268, 9.96104958e-03, -2.8885324e-06, 3.52893942e-10, -1.52964132e-14,
      3.08292386e+04, -22.4831282]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: IC4H5
  composition: {C: 4, H: 5}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [2.00881066, 0.0250340684, 4.47930427e-06, -2.63989791e-08, 1.3443288e-11,
      3.62069792e+04, 15.9913722]
    - [9.84674574, 0.0117404333, -3.4217147e-06, 4.19233616e-10, -1.8205713e-14,
      3.36372802e+04, -26.4810515]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 5.18
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: C4H6
  composition: {C: 4, H: 6}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.10599669, 5.05575563e-03, 5.83885454e-05, -8.05950198e-08, 3.27447711e-11,
      1.15092468e+04, 8.42978067]
    - [9.13356897, 0.0142245206, -4.1419597e-06, 5.05783108e-10, -2.18639864e-14,
      9018.92001, -23.0449129]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.72
    well-depth: 357.0
    rotational-relaxation: 1.0
- name: C4H7
  composition: {C: 4, H: 7}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [4.54746808, 4.6377146e-03, 6.61340221e-05, -8.97456502e-08, 3.61716165e-11,
      1.43843217e+04, 7.30313471]
    - [9.81284244, 0.0160745776, -4.69258014e-06, 5.7529787e-10, -2.4966613e-14,
      1.16684628e+04, -26.1501815]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.72
    well-depth: 357.1
    rotational-relaxation: 1.0
- name: C4H81
  composition: {C: 4, H: 8}
  thermo:
    model: NASA7
    temperature-ranges: [200.0, 1000.0, 6000.0]
    data:
    - [5.13226136, 5.33862838e-03, 6.0292896e-05, -7.60364685e-08, 2.87324693e-11,
      -2167.18358, 3.8293681]
    - [9.91777512, 0.018324682, -5.42158713e-06, 6.67929207e-10, -2.90126053e-14,
      -4964.69947, -27.734364]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 4.65
    well-depth: 355.0
    rotational-relaxation: 1.0
- name: NC12H26
  composition: {C: 12, H: 26}
  thermo:
    model: NASA7
    temperature-ranges: [300.0, 1391.0, 6000.0]
    data:
    - [-2.62181594, 0.147237711, -9.43970271e-05, 3.07441268e-08, -4.0360223e-12,
      -4.00654253e+04, 50.0994626]
    - [46.9715295, 0.042711289, -1.1727561e-05, 1.3737169e-09, -5.7405502e-14,
      -5.87475609e+04, -220.802094]
  transport:
    model: gas
    geometry: nonlinear
    diameter: 7.047
    well-depth: 789.98
    rotational-relaxation: 1.0
  note: 1/2/7THERM

reactions:
- equation: H + O2 <=> O + OH  # Reaction 1
  rate-constant: {A: 1.0399e+14, b: 0.0, Ea: 1.531e+04}
- equation: H2 + O <=> H + OH  # Reaction 2
  rate-constant: {A: 3.649e+12, b: 0.0, Ea: 7950.0}
  duplicate: true
- equation: H2 + O <=> H + OH  # Reaction 3
  rate-constant: {A: 7.6025e+14, b: 0.0, Ea: 1.918e+04}
  duplicate: true
- equation: H2 + OH <=> H + H2O  # Reaction 4
  rate-constant: {A: 2.1578e+08, b: 1.51, Ea: 3437.0}
- equation: 2 OH <=> H2O + O  # Reaction 5
  rate-constant: {A: 3.35e+04, b: 2.42, Ea: -1928.0}
- equation: H2 + M <=> 2 H + M  # Reaction 6
  type: three-body
  rate-constant: {A: 3.8767e+19, b: -1.4, Ea: 1.0439e+05}
  efficiencies: {AR: 0.0, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.9, CO2: 3.8, H2: 2.5, H2O: 12.0}
- equation: H2 + AR <=> 2 H + AR  # Reaction 7
  rate-constant: {A: 5.84e+18, b: -1.1, Ea: 1.0439e+05}
- equation: 2 O + M <=> O2 + M  # Reaction 8
  type: three-body
  rate-constant: {A: 6.16e+15, b: -0.5, Ea: 0.0}
  efficiencies: {AR: 0.0, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.9, CO2: 3.8, H2: 2.5, H2O: 12.0}
- equation: 2 O + AR <=> O2 + AR  # Reaction 9
  rate-constant: {A: 1.89e+13, b: 0.0, Ea: -1788.0}
- equation: H + O + M <=> OH + M  # Reaction 10
  type: three-body
  rate-constant: {A: 4.7124e+18, b: -1.0, Ea: 0.0}
  efficiencies: {AR: 0.75, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.9, CO2: 3.8, H2: 2.5, H2O: 12.0}
- equation: H2O + M <=> H + OH + M  # Reaction 11
  type: three-body
  rate-constant: {A: 5.903e+27, b: -3.32, Ea: 1.208e+05}
  efficiencies: {AR: 1.0, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 7.0, CO: 1.9, CO2: 3.8, H2: 3.0, H2O: 0.0, N2: 2.0, O2: 1.5}
- equation: H2O + H2O <=> H + OH + H2O  # Reaction 12
  rate-constant: {A: 1.01e+26, b: -2.44, Ea: 1.202e+05}
- equation: H + O2 (+ M) <=> HO2 (+ M)  # Reaction 13
  type: falloff
  low-P-rate-constant: {A: 7.2417e+20, b: -1.72, Ea: 525.0}
  high-P-rate-constant: {A: 5.2863e+12, b: 0.44, Ea: 0.0}
  Troe: {A: 0.5, T3: 30.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.6867116639685282, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0,
    C3H6: 4.0, CH2O: 2.5, CH4: 2.0, CO: 1.9, CO2: 2.98148670778874, H2: 2.0,
    H2O: 13.76974842661546, N2: 1.0, O2: 0.78}
- equation: H + HO2 <=> H2 + O2  # Reaction 14
  rate-constant: {A: 3.2729e+06, b: 2.09, Ea: -1455.0}
- equation: H + HO2 <=> 2 OH  # Reaction 15
  rate-constant: {A: 6.36e+13, b: 0.0, Ea: 300.0}
- equation: H + HO2 <=> H2O + O  # Reaction 16
  rate-constant: {A: 1.6131e+12, b: 0.0, Ea: 0.0}
- equation: HO2 + O <=> O2 + OH  # Reaction 17
  rate-constant: {A: 1.7208e+13, b: 0.0, Ea: -445.0}
- equation: HO2 + OH <=> H2O + O2  # Reaction 18
  rate-constant: {A: 7.6368e+12, b: 0.0, Ea: -1093.0}
  duplicate: true
- equation: HO2 + OH <=> H2O + O2  # Reaction 19
  rate-constant: {A: 4.5e+14, b: 0.0, Ea: 1.093e+04}
  duplicate: true
- equation: 2 HO2 <=> H2O2 + O2  # Reaction 20
  rate-constant: {A: 1.94e+11, b: 0.0, Ea: -1409.0}
  duplicate: true
- equation: 2 HO2 <=> H2O2 + O2  # Reaction 21
  rate-constant: {A: 1.03e+14, b: 0.0, Ea: 1.104e+04}
  duplicate: true
- equation: H2O2 (+ M) <=> 2 OH (+ M)  # Reaction 22
  type: falloff
  low-P-rate-constant: {A: 2.3968e+24, b: -2.3, Ea: 4.875e+04}
  high-P-rate-constant: {A: 1.9252e+12, b: 0.9, Ea: 4.875e+04}
  Troe: {A: 0.58, T3: 30.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.9859595379900199, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0,
    CH2O: 2.5, CH4: 2.0, CO: 1.5, CO2: 1.6, H2: 3.7, H2O: 7.5, H2O2: 7.7,
    N2: 1.5, O2: 1.2}
- equation: H + H2O2 <=> H2O + OH  # Reaction 23
  rate-constant: {A: 2.41e+13, b: 0.0, Ea: 3970.0}
- equation: H + H2O2 <=> H2 + HO2  # Reaction 24
  rate-constant: {A: 4.82e+13, b: 0.0, Ea: 7950.0}
- equation: H2O2 + O <=> HO2 + OH  # Reaction 25
  rate-constant: {A: 9.63e+06, b: 2.0, Ea: 3970.0}
- equation: H2O2 + OH <=> H2O + HO2  # Reaction 26
  rate-constant: {A: 1.7611e+12, b: 0.0, Ea: 318.0}
  duplicate: true
- equation: H2O2 + OH <=> H2O + HO2  # Reaction 27
  rate-constant: {A: 7.631e+13, b: 0.0, Ea: 7270.0}
  duplicate: true
- equation: CO + O (+ M) <=> CO2 (+ M)  # Reaction 28
  type: falloff
  low-P-rate-constant: {A: 1.5888e+21, b: -2.1, Ea: 5500.0}
  high-P-rate-constant: {A: 1.2029e+13, b: -0.31, Ea: 6943.0}
  efficiencies: {AR: 0.87, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.9, CO2: 3.8, H2: 2.5, H2O: 12.0}
- equation: CO + O2 <=> CO2 + O  # Reaction 29
  rate-constant: {A: 2.0406e+12, b: 0.0, Ea: 4.77e+04}
- equation: CO + OH <=> CO2 + H  # Reaction 30
  rate-constant: {A: 6.7547e+04, b: 2.05, Ea: -356.0}
  duplicate: true
- equation: CO + OH <=> CO2 + H  # Reaction 31
  rate-constant: {A: 5.2148e+12, b: -0.66, Ea: 332.0}
  duplicate: true
- equation: CO + HO2 <=> CO2 + OH  # Reaction 32
  rate-constant: {A: 1.57e+05, b: 2.18, Ea: 1.7944e+04}
- equation: HCO + M <=> CO + H + M  # Reaction 33
  type: three-body
  rate-constant: {A: 5.3789e+17, b: -1.2, Ea: 1.7734e+04}
  efficiencies: {AR: 0.9683651587783325, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0,
    C3H6: 4.0, CH2O: 2.5, CH4: 2.0, CO: 1.5, CO2: 2.0, H2O: 12.0}
- equation: H + HCO <=> CO + H2  # Reaction 34
  rate-constant: {A: 8.9578e+13, b: 0.0, Ea: 0.0}
- equation: HCO + O <=> CO + OH  # Reaction 35
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: HCO + O <=> CO2 + H  # Reaction 36
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: HCO + OH <=> CO + H2O  # Reaction 37
  rate-constant: {A: 1.08e+14, b: 0.0, Ea: 0.0}
- equation: HCO + O2 <=> CO + HO2  # Reaction 38
  rate-constant: {A: 5.9024e+06, b: 1.9, Ea: -1370.0}
- equation: HCO + HO2 => CO2 + H + OH  # Reaction 39
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: CH2 + H (+ M) <=> CH3 (+ M)  # Reaction 40
  type: falloff
  low-P-rate-constant: {A: 1.39e+34, b: -5.04, Ea: 7400.0}
  high-P-rate-constant: {A: 2.13e+13, b: 0.32, Ea: 0.0}
  Troe: {A: 0.405, T3: 258.0, T1: 2811.0, T2: 9908.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: CH2 + O => CO + 2 H  # Reaction 41
  rate-constant: {A: 8.7587e+13, b: 0.0, Ea: 0.0}
- equation: CH2 + OH <=> CH2O + H  # Reaction 42
  rate-constant: {A: 3.3016e+13, b: 0.12, Ea: -162.0}
- equation: CH2 + HO2 <=> CH2O + OH  # Reaction 43
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 0.0}
- equation: CH2 + H2 <=> CH3 + H  # Reaction 44
  rate-constant: {A: 3.7908e+05, b: 2.3, Ea: 7351.0}
- equation: CH2 + O2 => CO + H + OH  # Reaction 45
  rate-constant: {A: 2.516e+12, b: 0.0, Ea: 1000.0}
- equation: CH2 + O2 => CO2 + 2 H  # Reaction 46
  rate-constant: {A: 1.6707e+12, b: 0.0, Ea: 1000.0}
- equation: CH2 + O2 <=> CH2O + O  # Reaction 47
  rate-constant: {A: 1.57e+12, b: 0.0, Ea: 1000.0}
- equation: CH2 + O2 <=> CO2 + H2  # Reaction 48
  rate-constant: {A: 1.83e+12, b: 0.0, Ea: 1000.0}
- equation: CH2 + O2 <=> CO + H2O  # Reaction 49
  rate-constant: {A: 5.2e+11, b: 0.0, Ea: 1000.0}
- equation: 2 CH2 => C2H2 + 2 H  # Reaction 50
  rate-constant: {A: 2.0e+14, b: 0.0, Ea: 1.0989e+04}
- equation: 2 CH2 <=> H2 + H2CC  # Reaction 51
  rate-constant: {A: 1.6e+15, b: 0.0, Ea: 1.1944e+04}
- equation: CH2(S) + N2 <=> CH2 + N2  # Reaction 52
  rate-constant: {A: 1.2e+13, b: 0.0, Ea: 471.0}
- equation: AR + CH2(S) <=> AR + CH2  # Reaction 53
  rate-constant: {A: 9.0e+12, b: 0.0, Ea: 600.0}
- equation: CH2(S) + O => CO + 2 H  # Reaction 54
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: CH2(S) + OH <=> CH2O + H  # Reaction 55
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: CH2(S) + H2 <=> CH3 + H  # Reaction 56
  rate-constant: {A: 6.8e+13, b: 0.0, Ea: 0.0}
- equation: CH2(S) + O2 <=> CH2 + O2  # Reaction 57
  rate-constant: {A: 3.13e+13, b: 0.0, Ea: 0.0}
- equation: CH2(S) + H2O <=> CH2 + H2O  # Reaction 58
  rate-constant: {A: 1.51e+13, b: 0.0, Ea: -431.0}
- equation: CH2(S) + H2O <=> CH2O + H2  # Reaction 59
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 3.36e+22, b: -3.33, Ea: 3950.0}
  - {P: 0.9999999999999999 atm, A: 4.8e+23, b: -3.63, Ea: 5220.0}
  - {P: 2.999999999999998 atm, A: 6.85e+23, b: -3.66, Ea: 5820.0}
  - {P: 9.999999999999991 atm, A: 1.53e+24, b: -3.73, Ea: 6820.0}
  - {P: 30.000000000000014 atm, A: 8.75e+23, b: -3.62, Ea: 7655.0}
  - {P: 99.99999999999986 atm, A: 1.27e+22, b: -3.06, Ea: 7950.0}
- equation: CH2(S) + H2O2 <=> CH3O + OH  # Reaction 60
  rate-constant: {A: 1.29e+14, b: -0.14, Ea: 0.0}
- equation: CH2(S) + CO <=> CH2 + CO  # Reaction 61
  rate-constant: {A: 9.0e+12, b: 0.0, Ea: 0.0}
- equation: CH2(S) + CO2 <=> CH2 + CO2  # Reaction 62
  rate-constant: {A: 1.33e+13, b: 0.0, Ea: 0.0}
- equation: CH2(S) + CO2 <=> CH2O + CO  # Reaction 63
  rate-constant: {A: 6.62e+12, b: 0.0, Ea: 0.0}
- equation: H + HCO (+ M) <=> CH2O (+ M)  # Reaction 64
  type: falloff
  low-P-rate-constant: {A: 4.0439e+34, b: -5.53, Ea: 6128.0}
  high-P-rate-constant: {A: 1.7951e+14, b: -0.03, Ea: -142.0}
  Troe: {A: 0.782, T3: 271.0, T1: 2755.0, T2: 6570.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: CH2O (+ M) <=> CO + H2 (+ M)  # Reaction 65
  type: falloff
  low-P-rate-constant: {A: 4.4e+38, b: -6.1, Ea: 9.4e+04}
  high-P-rate-constant: {A: 3.7e+13, b: 0.0, Ea: 7.198e+04}
  Troe: {A: 0.932, T3: 197.00000000000003, T1: 1540.0, T2: 1.03e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: CH2O + H <=> H2 + HCO  # Reaction 66
  rate-constant: {A: 5.3963e+12, b: 0.36, Ea: 4609.0}
- equation: CH2O + H => CO + H2 + H  # Reaction 67
  rate-constant: {A: 1.7316e+13, b: 0.58, Ea: 1.4395e+04}
- equation: CH2O + O <=> HCO + OH  # Reaction 68
  rate-constant: {A: 7.2986e+15, b: -0.697, Ea: 5201.8}
- equation: CH2O + O => CO + H + OH  # Reaction 69
  rate-constant: {A: 2.7101e+21, b: -1.903, Ea: 2.2676e+04}
- equation: CH2O + OH <=> H2O + HCO  # Reaction 70
  rate-constant: {A: 1.2126e+10, b: 0.975, Ea: 24.66}
- equation: CH2O + OH => CO + H + H2O  # Reaction 71
  rate-constant: {A: 4.0551e+11, b: 0.692, Ea: 9370.9}
- equation: CH2O + O2 <=> HCO + HO2  # Reaction 72
  rate-constant: {A: 3.149e+05, b: 2.5, Ea: 3.646e+04}
- equation: CH2O + HO2 <=> H2O2 + HCO  # Reaction 73
  rate-constant: {A: 4.9957e+04, b: 2.5, Ea: 1.021e+04}
- equation: CH2 + CH2O <=> CH3 + HCO  # Reaction 74
  rate-constant: {A: 0.074, b: 4.21, Ea: 1120.0}
- equation: CH2(S) + CH2O <=> CH3 + HCO  # Reaction 75
  rate-constant: {A: 1.33e+13, b: 0.0, Ea: -550.0}
- equation: C2H + CH2O <=> C2H2 + HCO  # Reaction 76
  rate-constant: {A: 5400.0, b: 2.81, Ea: 5862.0}
- equation: C2H3 + CH2O <=> C2H4 + HCO  # Reaction 77
  rate-constant: {A: 5400.0, b: 2.81, Ea: 5862.0}
- equation: CH3 + H (+ M) <=> CH4 (+ M)  # Reaction 78
  type: falloff
  low-P-rate-constant: {A: 1.2779e+36, b: -5.57, Ea: 3818.0}
  high-P-rate-constant: {A: 2.1231e+14, b: 0.0, Ea: 0.0}
  Troe: {A: 0.37, T3: 3315.0, T1: 61.0, T2: 9.0e+04}
  efficiencies: {AR: 0.7411522103103376, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0,
    C3H6: 4.0, CH2O: 2.5, CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 5.56253976195153}
- equation: CH3 + O <=> CH2O + H  # Reaction 79
  rate-constant: {A: 5.7625e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + O => CO + H + H2  # Reaction 80
  rate-constant: {A: 2.31e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + OH <=> CH2 + H2O  # Reaction 81
  rate-constant: {A: 4.29e+04, b: 2.57, Ea: 3998.0}
- equation: CH3 + OH <=> CH2(S) + H2O  # Reaction 82
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 5.1997e+16, b: -1.12, Ea: 1620.0}
  - {P: 0.9999999999999999 atm, A: 8.691e+16, b: -1.16, Ea: 2765.0}
  - {P: 2.999999999999998 atm, A: 1.0622e+16, b: -0.87, Ea: 3100.0}
  - {P: 9.999999999999991 atm, A: 1.4856e+14, b: -0.31, Ea: 3170.0}
  - {P: 30.000000000000014 atm, A: 4.1004e+11, b: 0.44, Ea: 2880.0}
  - {P: 99.99999999999986 atm, A: 7.2871e+10, b: 0.66, Ea: 3793.0}
- equation: CH3 + OH <=> CH2O + H2  # Reaction 83
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 3.9441e+11, b: 0.14, Ea: -483.0}
  - {P: 0.9999999999999999 atm, A: 1.439e+13, b: -0.27, Ea: 1284.0}
  - {P: 2.999999999999998 atm, A: 8.9754e+13, b: -0.47, Ea: 2446.0}
  - {P: 9.999999999999991 atm, A: 1.6309e+14, b: -0.51, Ea: 3615.0}
  - {P: 30.000000000000014 atm, A: 1.066e+13, b: -0.14, Ea: 4100.0}
  - {P: 99.99999999999986 atm, A: 1.9614e+10, b: 0.68, Ea: 3960.0}
- equation: CH3 + HO2 <=> CH4 + O2  # Reaction 84
  rate-constant: {A: 8.4356e+04, b: 2.23, Ea: -3022.0}
- equation: CH3 + HO2 <=> CH3O + OH  # Reaction 85
  rate-constant: {A: 7.619e+12, b: 0.0, Ea: -590.0}
- equation: CH3 + O2 <=> CH3O + O  # Reaction 86
  rate-constant: {A: 8.2587e+12, b: 0.0, Ea: 2.8297e+04}
- equation: CH3 + O2 <=> CH2O + OH  # Reaction 87
  rate-constant: {A: 117.18, b: 2.86, Ea: 9768.0}
- equation: CH2 + CH3 <=> C2H4 + H  # Reaction 88
  rate-constant: {A: 1.127e+14, b: 0.0, Ea: 0.0}
- equation: CH2(S) + CH3 <=> C2H4 + H  # Reaction 89
  rate-constant: {A: 1.4e+13, b: 0.0, Ea: -497.0}
- equation: 2 CH3 (+ M) <=> C2H6 (+ M)  # Reaction 90
  type: falloff
  low-P-rate-constant: {A: 1.7034e+50, b: -9.67, Ea: 6220.0}
  high-P-rate-constant: {A: 2.0402e+16, b: -0.97, Ea: 620.0}
  Troe: {A: 0.532, T3: 151.0, T1: 1038.0, T2: 4970.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: 2 CH3 <=> C2H5 + H  # Reaction 91
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 9.3694e+12, b: 0.07, Ea: 1.1135e+04}
  - {P: 0.9999999999999999 atm, A: 3.1455e+12, b: 0.23, Ea: 1.2e+04}
  - {P: 2.999999999999998 atm, A: 1.7534e+11, b: 0.6, Ea: 1.22e+04}
  - {P: 9.999999999999991 atm, A: 7.1342e+08, b: 1.29, Ea: 1.2e+04}
  - {P: 30.000000000000014 atm, A: 7.2814e+05, b: 2.19, Ea: 1.14e+04}
  - {P: 99.99999999999986 atm, A: 133.85, b: 3.18, Ea: 1.05e+04}
- equation: CH3 + HCO <=> CH4 + CO  # Reaction 92
  rate-constant: {A: 2.62e+13, b: 0.0, Ea: 0.0}
- equation: CH2O + CH3 <=> CH4 + HCO  # Reaction 93
  rate-constant: {A: 34.78, b: 3.36, Ea: 4310.0}
- equation: CH3O (+ M) <=> CH2O + H (+ M)  # Reaction 94
  type: falloff
  low-P-rate-constant: {A: 6.02e+16, b: -0.55, Ea: 1.802e+04}
  high-P-rate-constant: {A: 1.13e+10, b: 1.21, Ea: 2.408e+04}
  Troe: {A: 0.341, T3: 28.0, T1: 1000.0, T2: 2339.0}
  efficiencies: {AR: 0.85, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: CH3O + H <=> CH2O + H2  # Reaction 95
  rate-constant: {A: 3.79e+13, b: 0.0, Ea: 596.0}
- equation: CH3O + H <=> CH3 + OH  # Reaction 96
  rate-constant: {A: 3.88e+14, b: -0.26, Ea: -26.0}
- equation: CH3O + H <=> CH2(S) + H2O  # Reaction 97
  rate-constant: {A: 1.97e+11, b: 0.41, Ea: 243.0}
- equation: CH3O + O <=> CH2O + OH  # Reaction 98
  rate-constant: {A: 3.78e+12, b: 0.0, Ea: 0.0}
- equation: CH3O + OH <=> CH2O + H2O  # Reaction 99
  rate-constant: {A: 1.81e+13, b: 0.0, Ea: 0.0}
- equation: CH3O + HO2 <=> CH2O + H2O2  # Reaction 100
  rate-constant: {A: 3.01e+11, b: 0.0, Ea: 0.0}
- equation: CH3O + O2 <=> CH2O + HO2  # Reaction 101
  rate-constant: {A: 6.32e+10, b: 0.0, Ea: 2603.0}
- equation: CH3 + CH3O <=> CH2O + CH4  # Reaction 102
  rate-constant: {A: 2.4e+13, b: 0.0, Ea: 0.0}
- equation: CH3O + CO <=> CH3 + CO2  # Reaction 103
  rate-constant: {A: 6.0e+12, b: 0.0, Ea: 1.1e+04}
- equation: CH4 + H <=> CH3 + H2  # Reaction 104
  rate-constant: {A: 6.9485e+05, b: 2.5, Ea: 9588.0}
- equation: CH4 + O <=> CH3 + OH  # Reaction 105
  rate-constant: {A: 6.93e+08, b: 1.56, Ea: 8485.0}
- equation: CH4 + OH <=> CH3 + H2O  # Reaction 106
  rate-constant: {A: 1.0e+06, b: 2.18, Ea: 2446.0}
- equation: CH4 + HO2 <=> CH3 + H2O2  # Reaction 107
  rate-constant: {A: 3.9686e+04, b: 2.5, Ea: 2.1e+04}
- equation: CH2 + CH4 <=> 2 CH3  # Reaction 108
  rate-constant: {A: 2.46e+06, b: 2.0, Ea: 8270.0}
- equation: CH2(S) + CH4 <=> 2 CH3  # Reaction 109
  rate-constant: {A: 1.87e+13, b: 0.0, Ea: -497.0}
- equation: C2H + CH4 <=> C2H2 + CH3  # Reaction 110
  rate-constant: {A: 1.3e+13, b: 0.0, Ea: 600.0}
- equation: C2H + O2 <=> CO + HCO  # Reaction 111
  rate-constant: {A: 1.63e+14, b: -0.35, Ea: 0.0}
- equation: H + HCCO <=> CH2(S) + CO  # Reaction 112
  rate-constant: {A: 1.32e+14, b: 0.0, Ea: 0.0}
- equation: C2H + OH <=> H + HCCO  # Reaction 113
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 0.0}
- equation: HCCO + O => 2 CO + H  # Reaction 114
  rate-constant: {A: 1.73e+14, b: -0.11, Ea: 0.0}
- equation: HCCO + O2 => CO + CO2 + H  # Reaction 115
  rate-constant: {A: 2.1074e+12, b: 0.0, Ea: 854.0}
- equation: HCCO + OH => CH2O + CO  # Reaction 116
  rate-constant: {A: 1.2316e+16, b: -0.59, Ea: 145.0}
- equation: HCCO + OH => CO + H + HCO  # Reaction 117
  rate-constant: {A: 5.6978e+13, b: 0.13, Ea: -215.0}
- equation: CH2 + HCCO <=> C2H3 + CO  # Reaction 118
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: 2 HCCO => C2H2 + 2 CO  # Reaction 119
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 0.0}
- equation: C2H2 (+ M) <=> H2CC (+ M)  # Reaction 120
  type: falloff
  low-P-rate-constant: {A: 3.0795e+15, b: -0.64, Ea: 4.97e+04}
  high-P-rate-constant: {A: 1.0055e+15, b: -0.52, Ea: 5.075e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: C2H + H2 <=> C2H2 + H  # Reaction 121
  rate-constant: {A: 1.9438e+06, b: 2.32, Ea: 882.0}
- equation: C2H + H (+ M) <=> C2H2 (+ M)  # Reaction 122
  type: falloff
  low-P-rate-constant: {A: 3.75e+33, b: -4.8, Ea: 1900.0}
  high-P-rate-constant: {A: 2.25e+13, b: 0.32, Ea: 0.0}
  Troe: {A: 0.646, T3: 13.2, T1: 1315.0, T2: 5566.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: C2H2 + O <=> H + HCCO  # Reaction 123
  rate-constant: {A: 9.6504e+08, b: 1.4, Ea: 2206.0}
- equation: C2H2 + O <=> CH2 + CO  # Reaction 124
  rate-constant: {A: 1.9961e+08, b: 1.4, Ea: 2206.0}
- equation: C2H2 + OH <=> CH2CO + H  # Reaction 125
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.02500000000000001 atm, A: 1.7405e+04, b: 2.28, Ea: -292.0}
  - {P: 0.10000000000000005 atm, A: 3.4581e+05, b: 1.92, Ea: 598.0}
  - {P: 0.9999999999999999 atm, A: 8.6222e+06, b: 1.55, Ea: 2106.0}
  - {P: 9.999999999999991 atm, A: 5.8398e+06, b: 1.65, Ea: 3400.0}
  - {P: 99.99999999999986 atm, A: 1.6718e+04, b: 2.45, Ea: 4477.0}
- equation: C2H2 + OH <=> C2H + H2O  # Reaction 126
  rate-constant: {A: 2.63e+06, b: 2.14, Ea: 1.706e+04}
- equation: C2H2 + OH <=> CH3 + CO  # Reaction 127
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.02500000000000001 atm, A: 4.37e+06, b: 1.4, Ea: 227.0}
  - {P: 0.10000000000000005 atm, A: 7.65e+07, b: 1.05, Ea: 1115.0}
  - {P: 0.9999999999999999 atm, A: 1.28e+09, b: 0.73, Ea: 2580.0}
  - {P: 9.999999999999991 atm, A: 4.31e+08, b: 0.92, Ea: 3736.0}
  - {P: 99.99999999999986 atm, A: 8.25e+05, b: 1.77, Ea: 4700.0}
- equation: C2H2 + HO2 <=> CH2CO + OH  # Reaction 128
  rate-constant: {A: 7.75e+06, b: 1.6, Ea: 1.53e+04}
- equation: C2H2 + HO2 => H + HCCO + OH  # Reaction 129
  rate-constant: {A: 2.1672e+07, b: 1.6, Ea: 1.53e+04}
- equation: H + H2CC <=> C2H2 + H  # Reaction 130
  rate-constant: {A: 5.0e+13, b: 0.0, Ea: 0.0}
- equation: H2CC + OH <=> CH2CO + H  # Reaction 131
  rate-constant: {A: 2.0e+13, b: 0.0, Ea: 0.0}
- equation: H2CC + O2 <=> 2 HCO  # Reaction 132
  rate-constant: {A: 6.0722e+12, b: 0.0, Ea: 0.0}
- equation: CH2 + CO (+ M) <=> CH2CO (+ M)  # Reaction 133
  type: falloff
  low-P-rate-constant: {A: 2.9246e+33, b: -5.11, Ea: 7095.0}
  high-P-rate-constant: {A: 8.8063e+11, b: 0.5, Ea: 4510.0}
  Troe: {A: 0.591, T3: 275.0, T1: 1226.0, T2: 5185.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: CH2CO + H <=> H2 + HCCO  # Reaction 134
  rate-constant: {A: 4.2e+07, b: 1.9, Ea: 1.185e+04}
- equation: CH2CO + H <=> CH3 + CO  # Reaction 135
  rate-constant: {A: 6.4437e+08, b: 1.45, Ea: 2780.0}
- equation: CH2CO + O <=> HCCO + OH  # Reaction 136
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 1.03e+04}
- equation: CH2CO + O <=> CH2 + CO2  # Reaction 137
  rate-constant: {A: 1.08e+12, b: 0.0, Ea: 1351.0}
- equation: CH2CO + O <=> 2 HCO  # Reaction 138
  rate-constant: {A: 3.61e+11, b: 0.0, Ea: 1351.0}
- equation: CH2CO + O <=> CH2O + CO  # Reaction 139
  rate-constant: {A: 3.2638e+11, b: 0.0, Ea: 1351.0}
- equation: CH2CO + OH <=> H2O + HCCO  # Reaction 140
  rate-constant: {A: 1.4854e+04, b: 2.74, Ea: 2220.0}
- equation: CH2CO + OH <=> CH3 + CO2  # Reaction 141
  rate-constant: {A: 6.2568e+11, b: 0.0, Ea: -1013.0}
- equation: C2H2 + H (+ M) <=> C2H3 (+ M)  # Reaction 142
  type: falloff
  low-P-rate-constant: {A: 2.7551e+27, b: -3.38, Ea: 847.0}
  high-P-rate-constant: {A: 4.2047e+08, b: 1.64, Ea: 2096.0}
  Troe: {A: 0.215, T3: 10.7, T1: 1043.0, T2: 2341.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: C2H3 + H <=> C2H2 + H2  # Reaction 143
  rate-constant: {A: 1.21e+12, b: 0.0, Ea: 0.0}
- equation: C2H3 + H <=> H2 + H2CC  # Reaction 144
  rate-constant: {A: 6.9378e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + O <=> CH2CO + H  # Reaction 145
  rate-constant: {A: 3.3016e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + OH <=> C2H2 + H2O  # Reaction 146
  rate-constant: {A: 2.2672e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + OH <=> CH3 + HCO  # Reaction 147
  rate-constant: {A: 1.7585e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + OH <=> CH2CHO + H  # Reaction 148
  rate-constant: {A: 4.18e+13, b: 0.0, Ea: 2870.0}
- equation: C2H3 + OH <=> CH4 + CO  # Reaction 149
  rate-constant: {A: 2.86e+11, b: 0.0, Ea: 1120.0}
- equation: C2H3 + O2 <=> CH2CHO + O  # Reaction 150
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 1.5283e+11, b: 0.32, Ea: 360.0}
  - {P: 0.9999999999999999 atm, A: 1.1147e+12, b: 0.08, Ea: 1020.0}
  - {P: 3.160000000000002 atm, A: 2.5351e+12, b: -0.02, Ea: 1530.0}
  - {P: 9.999999999999991 atm, A: 9.7089e+12, b: -0.16, Ea: 2460.0}
  - {P: 31.599999999999994 atm, A: 7.7312e+12, b: -0.1, Ea: 3340.0}
  - {P: 99.99999999999986 atm, A: 2.9846e+11, b: 0.34, Ea: 3750.0}
- equation: C2H3 + O2 <=> C2H2 + HO2  # Reaction 151
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 4340.0, b: 2.3, Ea: 590.0}
  - {P: 0.9999999999999999 atm, A: 5.6e+04, b: 1.99, Ea: 1362.0}
  - {P: 3.160000000000002 atm, A: 9.41e+04, b: 1.94, Ea: 1720.0}
  - {P: 9.999999999999991 atm, A: 1.13e+06, b: 1.65, Ea: 2820.0}
  - {P: 31.599999999999994 atm, A: 5.0e+06, b: 1.49, Ea: 3975.0}
  - {P: 99.99999999999986 atm, A: 1.57e+06, b: 1.67, Ea: 4820.0}
- equation: C2H3 + O2 <=> CH2O + HCO  # Reaction 152
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 4.5325e+16, b: -1.55, Ea: 1000.0}
  - {P: 0.9999999999999999 atm, A: 1.7664e+17, b: -1.71, Ea: 1391.0}
  - {P: 3.160000000000002 atm, A: 4.5713e+17, b: -1.82, Ea: 1890.0}
  - {P: 9.999999999999991 atm, A: 9.7056e+17, b: -1.89, Ea: 2745.0}
  - {P: 31.599999999999994 atm, A: 1.7567e+17, b: -1.64, Ea: 3360.0}
  - {P: 99.99999999999986 atm, A: 6.658e+14, b: -0.92, Ea: 3300.0}
- equation: C2H3 + O2 => CH2O + CO + H  # Reaction 153
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 8.7056e+16, b: -1.55, Ea: 1000.0}
  - {P: 0.9999999999999999 atm, A: 3.3944e+17, b: -1.71, Ea: 1391.0}
  - {P: 3.160000000000002 atm, A: 8.7855e+17, b: -1.82, Ea: 1890.0}
  - {P: 9.999999999999991 atm, A: 1.8689e+18, b: -1.89, Ea: 2745.0}
  - {P: 31.599999999999994 atm, A: 3.3704e+17, b: -1.64, Ea: 3360.0}
  - {P: 99.99999999999986 atm, A: 1.2779e+15, b: -0.92, Ea: 3300.0}
- equation: C2H3 + O2 => CO + H2 + HCO  # Reaction 154
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 6.56e+12, b: -0.47, Ea: 45.0}
  - {P: 0.9999999999999999 atm, A: 1.0e+13, b: -0.51, Ea: 236.0}
  - {P: 3.160000000000002 atm, A: 6.32e+13, b: -0.73, Ea: 965.0}
  - {P: 9.999999999999991 atm, A: 2.34e+14, b: -0.88, Ea: 1916.0}
  - {P: 31.599999999999994 atm, A: 5.36e+13, b: -0.65, Ea: 2600.0}
  - {P: 99.99999999999986 atm, A: 6.62e+11, b: -0.07, Ea: 2840.0}
- equation: C2H3 + O2 => H + HCCO + OH  # Reaction 155
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 1.16e+10, b: 0.28, Ea: 805.0}
  - {P: 0.9999999999999999 atm, A: 1.74e+11, b: -0.05, Ea: 1691.0}
  - {P: 3.160000000000002 atm, A: 9.4e+11, b: -0.24, Ea: 2454.0}
  - {P: 9.999999999999991 atm, A: 1.78e+13, b: -0.58, Ea: 3875.0}
  - {P: 31.599999999999994 atm, A: 8.8e+13, b: -0.74, Ea: 5400.0}
  - {P: 99.99999999999986 atm, A: 6.34e+13, b: -0.65, Ea: 6870.0}
- equation: C2H3 + O2 <=> CH2CO + OH  # Reaction 156
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 3.9e+09, b: 0.28, Ea: 805.0}
  - {P: 0.9999999999999999 atm, A: 5.8e+10, b: -0.05, Ea: 1691.0}
  - {P: 3.160000000000002 atm, A: 3.12e+11, b: -0.24, Ea: 2454.0}
  - {P: 9.999999999999991 atm, A: 5.9e+12, b: -0.58, Ea: 3875.0}
  - {P: 31.599999999999994 atm, A: 2.9e+13, b: -0.74, Ea: 5400.0}
  - {P: 99.99999999999986 atm, A: 2.11e+13, b: -0.65, Ea: 6870.0}
- equation: C2H3 + HO2 <=> CH2CHO + OH  # Reaction 157
  rate-constant: {A: 3.1762e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + CH3 <=> C2H2 + CH4  # Reaction 158
  rate-constant: {A: 1.0119e+13, b: 0.0, Ea: -765.0}
- equation: CH2CHO (+ M) <=> CH2CO + H (+ M)  # Reaction 159
  type: falloff
  low-P-rate-constant: {A: 1.5904e+29, b: -3.79, Ea: 4.358e+04}
  high-P-rate-constant: {A: 9.3208e+14, b: -0.15, Ea: 4.561e+04}
  Troe: {A: 0.796, T3: 100.0, T1: 4.999999999999999e+04, T2: 3.42e+04}
  efficiencies: {C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: CH2CHO (+ M) <=> CH3 + CO (+ M)  # Reaction 160
  type: falloff
  low-P-rate-constant: {A: 2.8858e+27, b: -3.18, Ea: 3.344e+04}
  high-P-rate-constant: {A: 3.6134e+12, b: 0.29, Ea: 4.033e+04}
  Troe: {A: 0.211, T3: 199.0, T1: 2032.0, T2: 1.117e+05}
  efficiencies: {C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: CH2CHO + H <=> CH3 + HCO  # Reaction 161
  rate-constant: {A: 6.1283e+14, b: 0.0, Ea: 716.0}
- equation: CH2CHO + H <=> CH2CO + H2  # Reaction 162
  rate-constant: {A: 1.1804e+13, b: 0.0, Ea: 0.0}
- equation: CH2CHO + H <=> CH4 + CO  # Reaction 163
  rate-constant: {A: 6.6e+12, b: 0.0, Ea: 2160.0}
- equation: CH2CHO + O => CH2 + CO2 + H  # Reaction 164
  rate-constant: {A: 1.4929e+14, b: 0.0, Ea: 0.0}
- equation: CH2CHO + OH <=> CH2CO + H2O  # Reaction 165
  rate-constant: {A: 1.2e+13, b: 0.0, Ea: 0.0}
- equation: CH2CHO + O2 => CH2O + CO + OH  # Reaction 166
  rate-constant: {A: 2.5728e+10, b: 0.0, Ea: 0.0}
- equation: CH2CHO + HO2 => CH3 + CO2 + OH  # Reaction 167
  rate-constant: {A: 2.8205e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + H (+ M) <=> C2H4 (+ M)  # Reaction 168
  type: falloff
  low-P-rate-constant: {A: 1.4e+30, b: -3.86, Ea: 3320.0}
  high-P-rate-constant: {A: 3.88e+13, b: 0.2, Ea: 0.0}
  Troe: {A: 0.782, T3: 207.49999999999997, T1: 2663.0, T2: 6095.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: C2H4 (+ M) <=> H2 + H2CC (+ M)  # Reaction 169
  type: falloff
  low-P-rate-constant: {A: 1.1184e+17, b: 0.0, Ea: 7.508e+04}
  high-P-rate-constant: {A: 2.5101e+15, b: 0.0, Ea: 8.623e+04}
  Troe: {A: 0.25, T3: 50.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: C2H4 + H <=> C2H3 + H2  # Reaction 170
  rate-constant: {A: 243.59, b: 3.62, Ea: 1.127e+04}
- equation: C2H4 + O <=> CH3 + HCO  # Reaction 171
  rate-constant: {A: 6.5439e+17, b: -1.717, Ea: 2891.6}
- equation: C2H4 + O <=> CH2CHO + H  # Reaction 172
  rate-constant: {A: 9.2886e+09, b: 0.948, Ea: 1723.5}
- equation: C2H4 + O <=> CH2 + CH2O  # Reaction 173
  rate-constant: {A: 5.768e+06, b: 1.991, Ea: 2857.9}
- equation: C2H4 + O <=> CH2CO + H2  # Reaction 174
  rate-constant: {A: 1.123e+17, b: -1.831, Ea: 3177.6}
- equation: C2H4 + OH <=> C2H3 + H2O  # Reaction 175
  rate-constant: {A: 1.9394e+04, b: 2.75, Ea: 2216.0}
- equation: C2H4 + OH <=> CH2O + CH3  # Reaction 176
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 555.0, b: 2.36, Ea: -181.0}
  - {P: 0.9999999999999999 atm, A: 1.78e+05, b: 1.68, Ea: 2060.0}
  - {P: 9.999999999999991 atm, A: 2.37e+09, b: 0.56, Ea: 6007.0}
  - {P: 99.99999999999986 atm, A: 2.76e+13, b: -0.5, Ea: 1.1456e+04}
- equation: C2H4 + O2 <=> C2H3 + HO2  # Reaction 177
  rate-constant: {A: 7.5353e+13, b: 0.0, Ea: 6.001e+04}
- equation: C2H4 + CH3 <=> C2H3 + CH4  # Reaction 178
  rate-constant: {A: 6.997e+07, b: 1.56, Ea: 1.663e+04}
- equation: C2H4 + H (+ M) <=> C2H5 (+ M)  # Reaction 179
  type: falloff
  low-P-rate-constant: {A: 1.9169e+39, b: -6.64, Ea: 5769.0}
  high-P-rate-constant: {A: 9.0557e+08, b: 1.46, Ea: 1355.0}
  Troe: {A: 0.594, T3: 2722.0, T1: 165.8, T2: 7396.0}
  efficiencies: {AR: 0.5670256032158684, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0,
    C3H6: 4.0, CH2O: 2.5, CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: C2H5 + H <=> C2H4 + H2  # Reaction 180
  rate-constant: {A: 1.81e+12, b: 0.0, Ea: 0.0}
- equation: C2H5 + O <=> CH2O + CH3  # Reaction 181
  rate-constant: {A: 5.0647e+13, b: 0.0, Ea: 0.0}
- equation: C2H5 + O <=> C2H4 + OH  # Reaction 182
  rate-constant: {A: 3.1936e+13, b: 0.0, Ea: 0.0}
- equation: C2H5 + OH <=> C2H4 + H2O  # Reaction 183
  rate-constant: {A: 1.605e+13, b: 0.0, Ea: 0.0}
- equation: C2H5 + O2 <=> C2H4 + HO2  # Reaction 184
  rate-constant: {A: 1.5359e+07, b: 1.09, Ea: -1975.0}
- equation: C2H5 + HO2 <=> C2H4 + H2O2  # Reaction 185
  rate-constant: {A: 3.01e+11, b: 0.0, Ea: 0.0}
- equation: C2H5 + HO2 => CH2O + CH3 + OH  # Reaction 186
  rate-constant: {A: 3.1e+13, b: 0.0, Ea: 0.0}
- equation: C2H5 + CH3 <=> C2H4 + CH4  # Reaction 187
  rate-constant: {A: 9.0e+11, b: 0.0, Ea: 0.0}
- equation: C2H5 + CH2O <=> C2H6 + HCO  # Reaction 188
  rate-constant: {A: 5500.0, b: 2.81, Ea: 5860.0}
- equation: C2H5 + H (+ M) <=> C2H6 (+ M)  # Reaction 189
  type: falloff
  low-P-rate-constant: {A: 2.1198e+41, b: -7.08, Ea: 6685.0}
  high-P-rate-constant: {A: 5.5499e+17, b: -0.99, Ea: 1580.0}
  Troe: {A: 0.842, T3: 125.0, T1: 2219.0, T2: 6882.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: C2H6 + H <=> C2H5 + H2  # Reaction 190
  rate-constant: {A: 1.2441e+08, b: 1.9, Ea: 7530.0}
- equation: C2H6 + O <=> C2H5 + OH  # Reaction 191
  rate-constant: {A: 1.5897e+05, b: 2.8, Ea: 5803.0}
- equation: C2H6 + O2 <=> C2H5 + HO2  # Reaction 192
  rate-constant: {A: 7.29e+05, b: 2.5, Ea: 4.916e+04}
- equation: C2H6 + OH <=> C2H5 + H2O  # Reaction 193
  rate-constant: {A: 9.15e+06, b: 2.0, Ea: 994.0}
- equation: C2H6 + HO2 <=> C2H5 + H2O2  # Reaction 194
  rate-constant: {A: 1.1305e+05, b: 2.5, Ea: 1.685e+04}
- equation: C2H6 + CH2(S) <=> C2H5 + CH3  # Reaction 195
  rate-constant: {A: 3.3e+13, b: 0.0, Ea: -660.0}
- equation: C2H6 + CH3 <=> C2H5 + CH4  # Reaction 196
  rate-constant: {A: 0.51226, b: 4.0, Ea: 8287.0}
- equation: C2H2 + CH3 <=> AC3H4 + H  # Reaction 197
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 2.4e+09, b: 0.91, Ea: 2.07e+04}
  - {P: 0.9999999999999999 atm, A: 5.14e+09, b: 0.86, Ea: 2.2153e+04}
  - {P: 9.999999999999991 atm, A: 5.1e+11, b: 0.35, Ea: 2.5e+04}
  - {P: 99.99999999999986 atm, A: 7.3e+12, b: 0.11, Ea: 2.85e+04}
- equation: AC3H4 + O <=> C2H4 + CO  # Reaction 198
  rate-constant: {A: 1.4e+13, b: 0.0, Ea: 1848.0}
- equation: AC3H4 + O <=> C2H2 + CH2O  # Reaction 199
  rate-constant: {A: 1.7e+12, b: 0.0, Ea: 1848.0}
- equation: AC3H4 + O <=> C2H3 + HCO  # Reaction 200
  rate-constant: {A: 1.2e+12, b: 0.0, Ea: 1848.0}
- equation: AC3H4 + OH <=> CH2CO + CH3  # Reaction 201
  rate-constant: {A: 3.12e+12, b: 0.0, Ea: -397.0}
- equation: AC3H4 + HO2 => C2H4 + CO + OH  # Reaction 202
  rate-constant: {A: 7.6e+12, b: 0.0, Ea: 1.8e+04}
- equation: AC3H4 <=> PC3H4  # Reaction 203
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.039000000000000035 atm, A: 6.917e+53, b: -12.18, Ea: 8.4276e+04}
  - {P: 0.9999999999999999 atm, A: 8.9015e+39, b: -7.8, Ea: 7.8446e+04}
  - {P: 9.999999999999991 atm, A: 5.4946e+48, b: -10.0, Ea: 8.8685e+04}
  - {P: 99.99999999999986 atm, A: 1.0668e+41, b: -7.57, Ea: 8.572e+04}
- equation: H + PC3H4 <=> AC3H4 + H  # Reaction 204
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 2.5054e+15, b: -0.26, Ea: 7600.0}
  - {P: 0.9999999999999999 atm, A: 6.8299e+17, b: -0.91, Ea: 1.0079e+04}
  - {P: 2.0 atm, A: 1.6339e+18, b: -1.0, Ea: 1.0756e+04}
  - {P: 4.999999999999996 atm, A: 2.1023e+18, b: -1.01, Ea: 1.1523e+04}
  - {P: 9.999999999999991 atm, A: 3.3768e+22, b: -2.18, Ea: 1.48e+04}
  - {P: 99.99999999999986 atm, A: 6.9715e+27, b: -3.58, Ea: 2.12e+04}
- equation: C2H2 + CH3 <=> H + PC3H4  # Reaction 205
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 4.071e+06, b: 1.86, Ea: 1.16e+04}
  - {P: 0.9999999999999999 atm, A: 2.316e+09, b: 1.1, Ea: 1.3644e+04}
  - {P: 9.999999999999991 atm, A: 9.9514e+11, b: 0.39, Ea: 1.62e+04}
  - {P: 99.99999999999986 atm, A: 1.8998e+12, b: 0.37, Ea: 1.81e+04}
- equation: O + PC3H4 <=> CH3 + HCCO  # Reaction 206
  rate-constant: {A: 7.6766e+12, b: 0.0, Ea: 2250.0}
- equation: O + PC3H4 <=> C2H4 + CO  # Reaction 207
  rate-constant: {A: 8.9547e+12, b: 0.0, Ea: 2250.0}
- equation: OH + PC3H4 <=> CH2CO + CH3  # Reaction 208
  rate-constant: {A: 1.56e+12, b: 0.0, Ea: -397.0}
- equation: HO2 + PC3H4 => C2H4 + CO + OH  # Reaction 209
  rate-constant: {A: 1.5e+07, b: 1.6, Ea: 1.53e+04}
- equation: C2H3 + HCO <=> C2H3CHO  # Reaction 210
  rate-constant: {A: 1.81e+13, b: 0.0, Ea: 0.0}
- equation: C2H3CHO + H => C2H3 + CO + H2  # Reaction 211
  rate-constant: {A: 2.05e+09, b: 1.16, Ea: 2405.0}
- equation: C2H3CHO + H <=> C2H4 + HCO  # Reaction 212
  rate-constant: {A: 5.1883e+13, b: 0.0, Ea: 4135.0}
- equation: C2H3CHO + O <=> CH2CHO + HCO  # Reaction 213
  rate-constant: {A: 1.4e+13, b: 0.0, Ea: 2405.0}
- equation: C2H3CHO + O => C2H3 + CO + OH  # Reaction 214
  rate-constant: {A: 2.9e+12, b: 0.0, Ea: 1880.0}
- equation: C2H3CHO + OH => C2H3 + CO + H2O  # Reaction 215
  rate-constant: {A: 5.94e+06, b: 1.98, Ea: -1635.0}
- equation: C2H3CHO + O2 => C2H3 + CO + HO2  # Reaction 216
  rate-constant: {A: 1.0e+13, b: 0.0, Ea: 4.07e+04}
- equation: C2H3CHO + HO2 => C2H3 + CO + H2O2  # Reaction 217
  rate-constant: {A: 3.01e+12, b: 0.0, Ea: 1.192e+04}
- equation: C2H3CHO + HO2 => CH2CHO + HCO + OH  # Reaction 218
  rate-constant: {A: 1.05e+12, b: 0.0, Ea: 1.42e+04}
- equation: C2H3CHO + CH3 => C2H3 + CH4 + CO  # Reaction 219
  rate-constant: {A: 2.9312e+06, b: 1.78, Ea: 5911.0}
- equation: C2H3CHO + C2H3 => C2H4 + CO + C2H3  # Reaction 220
  rate-constant: {A: 1.74e+12, b: 0.0, Ea: 8440.0}
- equation: C2H3CHO + C3H5 => C2H3 + C3H6 + CO  # Reaction 221
  rate-constant: {A: 6.3e+07, b: 1.8, Ea: 1.82e+04}
- equation: C2H2 + CH3 <=> C3H5  # Reaction 222
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 8.2e+53, b: -13.32, Ea: 3.32e+04}
  - {P: 0.9999999999999999 atm, A: 2.68e+53, b: -12.82, Ea: 3.573e+04}
  - {P: 9.999999999999991 atm, A: 4.4e+49, b: -11.4, Ea: 3.67e+04}
  - {P: 99.99999999999986 atm, A: 3.8e+44, b: -9.63, Ea: 3.76e+04}
- equation: AC3H4 + H <=> C3H5  # Reaction 223
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 1.0509e+62, b: -14.67, Ea: 2.6e+04}
  - {P: 0.9999999999999999 atm, A: 1.6622e+59, b: -13.54, Ea: 2.6949e+04}
  - {P: 9.999999999999991 atm, A: 2.6246e+52, b: -11.3, Ea: 2.54e+04}
  - {P: 99.99999999999986 atm, A: 7.5456e+41, b: -8.06, Ea: 2.13e+04}
- equation: H + PC3H4 <=> C3H5  # Reaction 224
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 1.1e+60, b: -14.56, Ea: 2.81e+04}
  - {P: 0.9999999999999999 atm, A: 4.91e+60, b: -14.37, Ea: 3.1644e+04}
  - {P: 9.999999999999991 atm, A: 2.2e+59, b: -13.61, Ea: 3.49e+04}
  - {P: 99.99999999999986 atm, A: 1.6e+55, b: -12.07, Ea: 3.75e+04}
- equation: C2H3 + CH3 <=> C3H5 + H  # Reaction 225
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 1.1139e+18, b: -1.34, Ea: 3677.0}
  - {P: 0.9999999999999999 atm, A: 6.4273e+13, b: -0.07, Ea: 3640.0}
  - {P: 9.999999999999991 atm, A: 3.1151e+06, b: 2.07, Ea: 2323.0}
  - {P: 99.99999999999986 atm, A: 3.9431e-03, b: 4.63, Ea: 129.0}
- equation: C2H4 + CH2 <=> C3H5 + H  # Reaction 226
  rate-constant: {A: 3.8741e+13, b: 0.0, Ea: 6000.0}
- equation: C2H4 + CH2(S) <=> C3H5 + H  # Reaction 227
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 1.13e+18, b: -1.43, Ea: 1213.0}
  - {P: 0.9999999999999999 atm, A: 7.4e+16, b: -1.04, Ea: 2330.0}
  - {P: 9.999999999999991 atm, A: 2.0e+11, b: 0.63, Ea: 2000.0}
  - {P: 99.99999999999986 atm, A: 18.3, b: 3.55, Ea: -34.0}
- equation: C2H3 + C2H5 <=> C3H5 + CH3  # Reaction 228
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 1.4549e+13, b: 0.0, Ea: 0.0}
  - {P: 0.9999999999999999 atm, A: 2.0389e+17, b: -1.15, Ea: 3370.0}
  - {P: 9.999999999999991 atm, A: 1.8796e+23, b: -2.75, Ea: 9420.0}
  - {P: 99.99999999999986 atm, A: 2.8672e+23, b: -2.67, Ea: 1.338e+04}
- equation: C3H5 + H <=> AC3H4 + H2  # Reaction 229
  rate-constant: {A: 1230.0, b: 3.04, Ea: 2582.0}
- equation: C3H5 + O <=> C2H3CHO + H  # Reaction 230
  rate-constant: {A: 6.0e+13, b: 0.0, Ea: 0.0}
- equation: C3H5 + O2 <=> AC3H4 + HO2  # Reaction 231
  rate-constant: {A: 2.06e+04, b: 2.19, Ea: 1.76e+04}
- equation: C3H5 + O2 <=> C2H3CHO + OH  # Reaction 232
  rate-constant: {A: 1.27e+14, b: -0.61, Ea: 2.1815e+04}
- equation: C3H5 + OH => C2H3CHO + 2 H  # Reaction 233
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 5.3e+37, b: -6.71, Ea: 2.9306e+04}
  - {P: 0.9999999999999999 atm, A: 4.2e+32, b: -5.16, Ea: 3.0126e+04}
  - {P: 9.999999999999991 atm, A: 1.6e+20, b: -1.56, Ea: 2.633e+04}
  - {P: 99.99999999999986 atm, A: 1.38e+15, b: -0.06, Ea: 2.68e+04}
- equation: C3H5 + OH <=> AC3H4 + H2O  # Reaction 234
  rate-constant: {A: 6.0e+12, b: 0.0, Ea: 0.0}
- equation: C3H5 + HO2 => C2H3CHO + H + OH  # Reaction 235
  rate-constant: {A: 5.4041e+13, b: 0.0, Ea: 2734.0}
- equation: C3H5 + HCO <=> C3H6 + CO  # Reaction 236
  rate-constant: {A: 6.0e+13, b: 0.0, Ea: 0.0}
- equation: C3H5 + CH3 <=> AC3H4 + CH4  # Reaction 237
  rate-constant: {A: 3.0e+12, b: -0.32, Ea: -131.0}
- equation: C2H3 + C3H5 <=> AC3H4 + C2H4  # Reaction 238
  rate-constant: {A: 1.0e+12, b: 0.0, Ea: 0.0}
- equation: C2H5 + C3H5 <=> AC3H4 + C2H6  # Reaction 239
  rate-constant: {A: 9.64e+11, b: 0.0, Ea: 0.0}
- equation: C2H5 + C3H5 <=> C2H4 + C3H6  # Reaction 240
  rate-constant: {A: 2.59e+12, b: 0.0, Ea: 0.0}
- equation: 2 C3H5 <=> AC3H4 + C3H6  # Reaction 241
  rate-constant: {A: 8.43e+10, b: 0.0, Ea: -262.0}
- equation: C2H3 + CH3 (+ M) <=> C3H6 (+ M)  # Reaction 242
  type: falloff
  low-P-rate-constant: {A: 4.996e+58, b: -11.94, Ea: 9770.0}
  high-P-rate-constant: {A: 2.9251e+13, b: 0.0, Ea: 0.0}
  Troe: {A: 0.175, T3: 1341.0, T1: 6.0e+04, T2: 1.014e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: C3H5 + H (+ M) <=> C3H6 (+ M)  # Reaction 243
  type: falloff
  low-P-rate-constant: {A: 1.2418e+60, b: -12.0, Ea: 5968.0}
  high-P-rate-constant: {A: 1.8673e+14, b: 0.0, Ea: 0.0}
  Troe: {A: 0.02, T3: 1097.0, T1: 1097.0, T2: 6860.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: C2H4 + CH2(S) <=> C3H6  # Reaction 244
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 3.27e+44, b: -10.14, Ea: 7600.0}
  - {P: 0.9999999999999999 atm, A: 4.65e+39, b: -8.31, Ea: 6974.0}
  - {P: 9.999999999999991 atm, A: 7.43e+31, b: -5.74, Ea: 5160.0}
  - {P: 99.99999999999986 atm, A: 2.48e+24, b: -3.35, Ea: 3517.0}
- equation: C2H4 + CH2(S) <=> C2H3 + CH3  # Reaction 245
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 5.3e+13, b: -0.09, Ea: 1123.0}
  - {P: 0.9999999999999999 atm, A: 1.5e+13, b: 0.12, Ea: 3000.0}
  - {P: 9.999999999999991 atm, A: 5.17e+09, b: 1.19, Ea: 3780.0}
  - {P: 99.99999999999986 atm, A: 4.5e+05, b: 2.43, Ea: 4790.0}
- equation: C3H6 + H <=> C3H5 + H2  # Reaction 246
  rate-constant: {A: 1.169e+06, b: 2.31, Ea: 4674.0}
- equation: C3H6 + H <=> C2H4 + CH3  # Reaction 247
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 1.0000000000000002e-03 atm, A: 1.5347e+09, b: 1.35, Ea: 2542.0}
  - {P: 0.039000000000000035 atm, A: 7.8527e+10, b: 0.87, Ea: 3600.0}
  - {P: 0.9999999999999999 atm, A: 2.6608e+12, b: 0.47, Ea: 5431.0}
  - {P: 9.999999999999991 atm, A: 1.1859e+17, b: -0.79, Ea: 9750.0}
  - {P: 99.99999999999986 atm, A: 2.6508e+18, b: -1.09, Ea: 1.318e+04}
- equation: C3H6 + O <=> C2H5 + HCO  # Reaction 248
  rate-constant: {A: 9.0e+05, b: 2.15, Ea: -795.0}
- equation: C3H6 + O <=> CH2CHO + CH3  # Reaction 249
  rate-constant: {A: 1.01e+06, b: 2.15, Ea: -795.0}
- equation: C3H6 + O => C2H3CHO + 2 H  # Reaction 250
  rate-constant: {A: 1.66e+06, b: 2.15, Ea: -795.0}
- equation: C3H6 + O <=> C3H5 + OH  # Reaction 251
  rate-constant: {A: 1.75e+11, b: 0.7, Ea: 5882.0}
- equation: C3H6 + O2 <=> C3H5 + HO2  # Reaction 252
  rate-constant: {A: 5.5172e+29, b: -4.412, Ea: 5.4372e+04}
- equation: C3H6 + OH <=> C3H5 + H2O  # Reaction 253
  rate-constant: {A: 1.9064e+06, b: 2.23, Ea: 1073.0}
- equation: C3H6 + HO2 <=> C3H5 + H2O2  # Reaction 254
  rate-constant: {A: 2.7e+04, b: 2.5, Ea: 1.234e+04}
- equation: C3H6 + HO2 => CH2CHO + CH3 + OH  # Reaction 255
  rate-constant: {A: 1.03e+12, b: 0.0, Ea: 1.42e+04}
- equation: C3H6 + CH3 <=> C3H5 + CH4  # Reaction 256
  rate-constant: {A: 49.61, b: 3.27, Ea: 7152.0}
- equation: C2H5 + C3H6 <=> C2H6 + C3H5  # Reaction 257
  rate-constant: {A: 16.9, b: 3.38, Ea: 7598.0}
- equation: C3H6 + H <=> IC3H7  # Reaction 258
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 1.0000000000000002e-03 atm, A: 1.1188e+38, b: -8.8, Ea: 6113.0}
  - {P: 0.039000000000000035 atm, A: 1.1577e+40, b: -8.93, Ea: 8340.0}
  - {P: 0.9999999999999999 atm, A: 6.6931e+37, b: -7.85, Ea: 8914.0}
  - {P: 9.999999999999991 atm, A: 2.1792e+34, b: -6.55, Ea: 8600.0}
  - {P: 99.99999999999986 atm, A: 2.1889e+29, b: -4.84, Ea: 7580.0}
- equation: H + IC3H7 <=> C3H6 + H2  # Reaction 259
  rate-constant: {A: 3.61e+12, b: 0.0, Ea: 0.0}
- equation: H + IC3H7 <=> C2H5 + CH3  # Reaction 260
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 4.51e+29, b: -4.49, Ea: 1.3643e+04}
  - {P: 0.9999999999999999 atm, A: 1.4e+28, b: -3.94, Ea: 1.5916e+04}
  - {P: 9.999999999999991 atm, A: 4.0e+24, b: -2.83, Ea: 1.7542e+04}
  - {P: 99.99999999999986 atm, A: 2.1e-05, b: 5.6, Ea: 3590.0}
- equation: IC3H7 + O2 <=> C3H6 + HO2  # Reaction 261
  rate-constant: {A: 3.1817e+10, b: 0.0, Ea: -2146.0}
- equation: IC3H7 + OH <=> C3H6 + H2O  # Reaction 262
  rate-constant: {A: 2.41e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + IC3H7 <=> C3H6 + CH4  # Reaction 263
  rate-constant: {A: 9.41e+10, b: 0.68, Ea: 0.0}
- equation: C2H + C2H2 <=> C4H2 + H  # Reaction 264
  rate-constant: {A: 9.6e+13, b: 0.0, Ea: 0.0}
- equation: C2H + C2H2 (+ M) <=> IC4H3 (+ M)  # Reaction 265
  type: falloff
  low-P-rate-constant: {A: 1.24e+31, b: -4.72, Ea: 1871.0}
  high-P-rate-constant: {A: 8.3e+10, b: 0.9, Ea: -363.0}
  Troe: {A: 1.0, T3: 100.0, T1: 5613.0, T2: 1.339e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: C4H2 + H <=> IC4H3  # Reaction 266
  rate-constant: {A: 1.1e+30, b: -4.92, Ea: 1.08e+04}
- equation: H + IC4H3 <=> C2H2 + H2CC  # Reaction 267
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 5.88e+26, b: -3.95, Ea: 7700.0}
  - {P: 0.9999999999999999 atm, A: 2.51e+20, b: -2.02, Ea: 6890.0}
  - {P: 9.999999999999991 atm, A: 3.36e+28, b: -4.28, Ea: 1.462e+04}
  - {P: 99.99999999999986 atm, A: 2.5e+34, b: -5.86, Ea: 2.176e+04}
- equation: H + IC4H3 <=> C4H2 + H2  # Reaction 268
  rate-constant: {A: 4.975e+13, b: 0.0, Ea: 0.0}
- equation: IC4H3 + OH <=> C4H2 + H2O  # Reaction 269
  rate-constant: {A: 4.0e+12, b: 0.0, Ea: 0.0}
- equation: IC4H3 + O2 <=> CH2CO + HCCO  # Reaction 270
  rate-constant: {A: 7.86e+16, b: -1.8, Ea: 0.0}
- equation: IC4H3 + O <=> H2CC + HCCO  # Reaction 271
  rate-constant: {A: 3.01e+13, b: 0.0, Ea: 0.0}
- equation: HO2 + IC4H3 => H2CC + HCCO + OH  # Reaction 272
  rate-constant: {A: 3.2229e+13, b: 0.0, Ea: 0.0}
- equation: CH3 + IC4H3 <=> C4H2 + CH4  # Reaction 273
  rate-constant: {A: 7.5063e+12, b: 0.0, Ea: -765.0}
- equation: CH4 + IC4H3 <=> C4H4 + CH3  # Reaction 274
  rate-constant: {A: 3.4888e+07, b: 1.59, Ea: 1.1406e+04}
- equation: C2H2 + H2CC (+ M) <=> C4H4 (+ M)  # Reaction 275
  type: falloff
  low-P-rate-constant: {A: 1.4e+60, b: -12.6, Ea: 1.132e+04}
  high-P-rate-constant: {A: 3.5e+05, b: 2.06, Ea: 1500.0}
  Troe: {A: 0.98, T3: 56.0, T1: 580.0, T2: 4164.0}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: H + IC4H3 <=> C4H4  # Reaction 276
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 2.4e+44, b: -9.77, Ea: 8974.0}
  - {P: 0.9999999999999999 atm, A: 2.88e+36, b: -7.13, Ea: 7080.0}
  - {P: 9.999999999999991 atm, A: 7.38e+28, b: -4.67, Ea: 5000.0}
  - {P: 99.99999999999986 atm, A: 1.54e+24, b: -3.17, Ea: 3640.0}
- equation: C4H4 + H <=> H2 + IC4H3  # Reaction 277
  rate-constant: {A: 3.33e+05, b: 2.53, Ea: 9240.0}
- equation: C2H2 + C2H3 <=> C4H4 + H  # Reaction 278
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.025999999999999995 atm, A: 5.3075e+14, b: -0.71, Ea: 6700.0}
  - {P: 0.9999999999999999 atm, A: 2.123e+18, b: -1.68, Ea: 1.06e+04}
  - {P: 9.999999999999991 atm, A: 5.2014e+16, b: -1.13, Ea: 1.18e+04}
  - {P: 99.99999999999986 atm, A: 6.1142e+20, b: -2.26, Ea: 1.525e+04}
- equation: C2H + C2H4 <=> C4H4 + H  # Reaction 279
  rate-constant: {A: 8.43e+13, b: 0.0, Ea: 0.0}
- equation: C4H4 + O <=> C2H2 + CH2 + CO  # Reaction 280
  rate-constant: {A: 6.0e+08, b: 1.45, Ea: -860.0}
- equation: C4H4 + OH <=> H2O + IC4H3  # Reaction 281
  rate-constant: {A: 1.55e+07, b: 2.0, Ea: 430.0}
- equation: C2H2 + C2H3 <=> IC4H5  # Reaction 282
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.025999999999999995 atm, A: 2.1e+36, b: -8.78, Ea: 9100.0}
  - {P: 0.9999999999999999 atm, A: 1.6e+46, b: -10.98, Ea: 1.86e+04}
  - {P: 9.999999999999991 atm, A: 5.1e+53, b: -12.64, Ea: 2.88e+04}
  - {P: 99.99999999999986 atm, A: 1.45e+56, b: -12.87, Ea: 3.55e+04}
- equation: C4H4 + H (+ M) <=> IC4H5 (+ M)  # Reaction 283
  type: falloff
  low-P-rate-constant: {A: 2.5173e+46, b: -9.19, Ea: -200.0}
  high-P-rate-constant: {A: 6.5449e+10, b: 0.86, Ea: 1200.0}
  Troe: {A: 0.4, T3: 50.0, T1: 9.0e+04, T2: 9.0e+04}
  efficiencies: {AR: 0.7, C2H2: 3.0, C2H4: 3.0, C2H6: 3.0, C3H6: 4.0, CH2O: 2.5,
    CH4: 2.0, CO: 1.5, CO2: 2.0, H2: 2.0, H2O: 6.0}
- equation: H + IC4H5 <=> C4H4 + H2  # Reaction 284
  rate-constant: {A: 3.0e+13, b: 0.0, Ea: 0.0}
- equation: 2 C2H3 <=> H + IC4H5  # Reaction 285
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.06599999999999998 atm, A: 6.94e+15, b: -1.1, Ea: 3570.0}
  - {P: 0.9999999999999999 atm, A: 4.0e+13, b: -0.37, Ea: 4340.0}
  - {P: 9.999999999999991 atm, A: 4.73e+06, b: 1.73, Ea: 3490.0}
  - {P: 50.00000000000001 atm, A: 1.61e+34, b: -6.02, Ea: 2.4e+04}
- equation: IC4H5 + O <=> C2H3 + CH2CO  # Reaction 286
  rate-constant: {A: 2.8138e+13, b: 0.0, Ea: 0.0}
- equation: IC4H5 + OH <=> C4H4 + H2O  # Reaction 287
  rate-constant: {A: 4.0e+12, b: 0.0, Ea: 0.0}
- equation: IC4H5 + O2 <=> CH2CHO + CH2CO  # Reaction 288
  rate-constant: {A: 2.16e+10, b: 0.0, Ea: 2500.0}
- equation: HO2 + IC4H5 <=> C4H6 + O2  # Reaction 289
  rate-constant: {A: 6.0e+11, b: 0.0, Ea: 0.0}
- equation: HO2 + IC4H5 => C2H3 + CH2CO + OH  # Reaction 290
  rate-constant: {A: 6.6e+12, b: 0.0, Ea: 0.0}
- equation: H2O2 + IC4H5 <=> C4H6 + HO2  # Reaction 291
  rate-constant: {A: 1.21e+10, b: 0.0, Ea: -596.0}
- equation: HCO + IC4H5 <=> C4H6 + CO  # Reaction 292
  rate-constant: {A: 5.0e+12, b: 0.0, Ea: 0.0}
- equation: CH3 + IC4H5 <=> C4H4 + CH4  # Reaction 293
  rate-constant: {A: 8.5112e+12, b: 0.0, Ea: -765.0}
- equation: 2 C2H3 <=> C4H6  # Reaction 294
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.06599999999999998 atm, A: 1.9473e+26, b: -4.24, Ea: 3376.0}
  - {P: 0.06599999999999998 atm, A: 4.6757e+35, b: -8.11, Ea: 5270.0}
  - {P: 0.9999999999999999 atm, A: 2.7605e+32, b: -5.88, Ea: 6050.0}
  - {P: 9.999999999999991 atm, A: 1.055e+26, b: -3.8, Ea: 4310.0}
  - {P: 50.00000000000001 atm, A: 3.7448e+21, b: -2.38, Ea: 2950.0}
- equation: C2H4 + H2CC <=> C4H6  # Reaction 295
  rate-constant: {A: 1.5732e+12, b: 0.0, Ea: 0.0}
- equation: C4H6 <=> C4H4 + H2  # Reaction 296
  rate-constant: {A: 2.5e+15, b: 0.0, Ea: 9.47e+04}
- equation: H + IC4H5 <=> C4H6  # Reaction 297
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.06599999999999998 atm, A: 6.07e+53, b: -12.79, Ea: 1.174e+04}
  - {P: 0.9999999999999999 atm, A: 3.9e+32, b: -5.91, Ea: 5970.0}
  - {P: 9.999999999999991 atm, A: 3.88e+37, b: -7.35, Ea: 8100.0}
  - {P: 50.00000000000001 atm, A: 2.22e+30, b: -5.06, Ea: 5890.0}
- equation: C4H6 + H <=> H2 + IC4H5  # Reaction 298
  rate-constant: {A: 5.0252e+05, b: 2.53, Ea: 9240.0}
- equation: C4H6 + H <=> CH3 + PC3H4  # Reaction 299
  rate-constant: {A: 2.0e+12, b: 0.0, Ea: 7000.0}
- equation: C4H6 + H <=> AC3H4 + CH3  # Reaction 300
  rate-constant: {A: 1.8744e+12, b: 0.0, Ea: 7000.0}
- equation: C2H3 + C2H4 <=> C4H6 + H  # Reaction 301
  rate-constant: {A: 1.6733e+05, b: 2.14, Ea: 2740.0}
- equation: C4H6 + O <=> IC4H5 + OH  # Reaction 302
  rate-constant: {A: 7.5e+06, b: 1.9, Ea: 3740.0}
- equation: C4H6 + OH <=> H2O + IC4H5  # Reaction 303
  rate-constant: {A: 2.1328e+06, b: 2.0, Ea: 430.0}
- equation: C2H3 + C2H3CHO <=> C4H6 + HCO  # Reaction 304
  rate-constant: {A: 2.8e+21, b: -2.44, Ea: 1.472e+04}
- equation: C2H3 + C3H6 <=> C4H6 + CH3  # Reaction 305
  rate-constant: {A: 7.23e+11, b: 0.0, Ea: 5000.0}
- equation: C4H6 + CH3 <=> CH4 + IC4H5  # Reaction 306
  rate-constant: {A: 1.0e+14, b: 0.0, Ea: 1.98e+04}
- equation: C2H3 + C4H6 <=> C2H4 + IC4H5  # Reaction 307
  rate-constant: {A: 2.5e+13, b: 0.0, Ea: 1.98e+04}
- equation: C3H5 + C4H6 <=> C3H6 + IC4H5  # Reaction 308
  rate-constant: {A: 5.0e+12, b: 0.0, Ea: 1.95e+04}
- equation: C4H6 + H <=> C4H7  # Reaction 309
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 6.5622e+52, b: -12.09, Ea: 1.76e+04}
  - {P: 0.9999999999999999 atm, A: 4.1276e+45, b: -9.7, Ea: 1.599e+04}
  - {P: 9.999999999999991 atm, A: 4.7457e+35, b: -6.57, Ea: 1.258e+04}
  - {P: 99.99999999999986 atm, A: 1.7499e+15, b: -0.44, Ea: 3520.0}
- equation: C4H7 + H <=> C3H5 + CH3  # Reaction 310
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 2.51e+32, b: -5.0, Ea: 1.32e+04}
  - {P: 0.9999999999999999 atm, A: 1.1295e+33, b: -5.1, Ea: 1.646e+04}
  - {P: 9.999999999999991 atm, A: 7.8438e+43, b: -8.11, Ea: 2.64e+04}
  - {P: 99.99999999999986 atm, A: 9.6845e+36, b: -6.0, Ea: 2.626e+04}
- equation: C4H7 + H <=> C4H6 + H2  # Reaction 311
  rate-constant: {A: 1.8e+12, b: 0.0, Ea: 0.0}
- equation: C4H7 + O <=> C3H5 + CH2O  # Reaction 312
  rate-constant: {A: 4.42e+13, b: 0.0, Ea: 0.0}
- equation: C4H7 + OH <=> C4H6 + H2O  # Reaction 313
  rate-constant: {A: 2.41e+13, b: 0.0, Ea: 0.0}
- equation: C4H7 + O2 <=> C4H6 + HO2  # Reaction 314
  rate-constant: {A: 5.8541e+10, b: 0.0, Ea: 0.0}
- equation: C4H7 + HO2 => C3H5 + CH2O + OH  # Reaction 315
  rate-constant: {A: 2.7388e+13, b: 0.0, Ea: 0.0}
- equation: C4H7 + HCO <=> C4H81 + CO  # Reaction 316
  rate-constant: {A: 6.0e+13, b: 0.0, Ea: 0.0}
- equation: C4H7 + CH3 <=> C4H6 + CH4  # Reaction 317
  rate-constant: {A: 1.2154e+13, b: 0.0, Ea: 0.0}
- equation: C2H3 + C2H5 <=> C4H81  # Reaction 318
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 8.85e+52, b: -13.2, Ea: 1.03e+04}
  - {P: 0.9999999999999999 atm, A: 1.03e+51, b: -12.2, Ea: 1.163e+04}
  - {P: 9.999999999999991 atm, A: 6.3e+40, b: -8.73, Ea: 9000.0}
  - {P: 99.99999999999986 atm, A: 2.2e+27, b: -4.43, Ea: 4850.0}
- equation: C3H5 + CH3 <=> C4H81  # Reaction 319
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 3.0488e+41, b: -8.84, Ea: 9250.0}
  - {P: 0.9999999999999999 atm, A: 6.4635e+31, b: -5.75, Ea: 6250.0}
  - {P: 9.999999999999991 atm, A: 1.2306e+23, b: -3.0, Ea: 3350.0}
  - {P: 99.99999999999986 atm, A: 1.3082e+17, b: -1.14, Ea: 1290.0}
- equation: C4H7 + H <=> C4H81  # Reaction 320
  type: pressure-dependent-Arrhenius
  rate-constants:
  - {P: 0.10000000000000005 atm, A: 2.4e+47, b: -10.6, Ea: 1.02e+04}
  - {P: 0.9999999999999999 atm, A: 1.54e+39, b: -7.84, Ea: 8230.0}
  - {P: 9.999999999999991 atm, A: 2.3e+28, b: -4.4, Ea: 4735.0}
  - {P: 99.99999999999986 atm, A: 3.52e+20, b: -1.95, Ea: 2160.0}
- equation: C4H81 + H <=> C2H4 + C2H5  # Reaction 321
  rate-constant: {A: 8.0e+21, b: -2.39, Ea: 1.118e+04}
- equation: C4H81 + H <=> C3H6 + CH3  # Reaction 322
  rate-constant: {A: 1.8351e+22, b: -2.39, Ea: 1.118e+04}
- equation: C4H81 + H <=> C4H7 + H2  # Reaction 323
  rate-constant: {A: 8.04e+06, b: 2.11, Ea: 3380.0}
- equation: C4H81 + O <=> C4H7 + OH  # Reaction 324
  rate-constant: {A: 1.5e+13, b: 0.0, Ea: 5760.0}
  duplicate: true
- equation: C4H81 + O <=> C4H7 + OH  # Reaction 325
  rate-constant: {A: 2.6e+13, b: 0.0, Ea: 4470.0}
  duplicate: true
- equation: C4H81 + OH <=> C4H7 + H2O  # Reaction 326
  rate-constant: {A: 4.2e+05, b: 2.4, Ea: -932.0}
- equation: C4H81 + O2 <=> C4H7 + HO2  # Reaction 327
  rate-constant: {A: 1.26e+12, b: 0.0, Ea: 3.49e+04}
- equation: C4H81 + HO2 <=> C4H7 + H2O2  # Reaction 328
  rate-constant: {A: 0.391, b: 3.97, Ea: 1.1702e+04}
- equation: C4H81 + CH3 <=> C4H7 + CH4  # Reaction 329
  rate-constant: {A: 161.0, b: 3.12, Ea: 5813.0}
- equation: NC12H26 => 4.05947 C2H4 + 0.644672 C3H6 + 0.266415 C4H81 + 0.88138
    CH3 + 1.11862 H  # Reaction 330
  rate-constant: {A: 1.1903e+27, b: -2.69, Ea: 8.84562e+04}
- equation: H + NC12H26 => 2.69249 C2H4 + 1.28519 C3H6 + 0.611553 C4H81
    + 0.313237 CH3 + 0.686763 H + H2  # Reaction 331
  rate-constant: {A: 0.15938, b: 4.76, Ea: 1309.4}
- equation: CH3 + NC12H26 => 2.69249 C2H4 + 1.28519 C3H6 + 0.611553 C4H81
    + 0.313237 CH3 + CH4 + 0.686763 H  # Reaction 332
  rate-constant: {A: 9.9171e-07, b: 5.95, Ea: 4759.0}
- equation: NC12H26 + OH => 2.69249 C2H4 + 1.28519 C3H6 + 0.611553 C4H81
    + 0.313237 CH3 + 0.686763 H + H2O  # Reaction 333
  rate-constant: {A: 1.6218e+10, b: 1.12, Ea: 21.8}
- equation: NC12H26 + O2 => 2.69249 C2H4 + 1.28519 C3H6 + 0.611553 C4H81
    + 0.313237 CH3 + 0.686763 H + HO2  # Reaction 334
  rate-constant: {A: 2.9102e+14, b: 0.05, Ea: 4.75566e+04}
- equation: HO2 + NC12H26 => 2.69249 C2H4 + 1.28519 C3H6 + 0.611553 C4H81
    + 0.313237 CH3 + 0.686763 H + H2O2  # Reaction 335
  rate-constant: {A: 4.004e+04, b: 2.87, Ea: 1.49189e+04}
- equation: NC12H26 + O => 2.69249 C2H4 + 1.28519 C3H6 + 0.611553 C4H81
    + 0.313237 CH3 + 0.686763 H + OH  # Reaction 336
  rate-constant: {A: 80.945, b: 3.87, Ea: 737.1}